What makes an adhesive tape stick and stay stuck

pro clima adhesive tape technology explained

Adhesive tapes have become widely established as bonding agents for use in sealing modern constructions, just as nails and screws are the standard solution for timber structures. Adhesive tapes can be used as bonding aids in a wide range applications in the creation of airtight building envelopes where several hundred metres of tape can often be used on a single building! They have to fulfil their functions for a number of decades to ensure that the building in question fulfils the standards expected by the designers and ultimately by the building client. This article provides an overview of adhesive technology and the key properties of adhesive tapes typically used in construction.

Dispersion Vs Solid Acrylic Glues

Adhesive tapes for the creation of air-tightness are generally manufactured using two main production methods. The majority ~ 85% are produced as dispersion adhesives.  Below we will outline the process involved and properties of a dispersion adhesive tape

In this process, acrylates dissolved in water are applied to the backing material in a liquid state. Emulsifiers are added to the dispersion to ensure that the dispersion remains homogeneous and that the acrylates dissolve in water in the first place. The function of these emulsifiers is to attract water.

The water is then evaporated in long drying chambers later in the production process.

The dissolved acrylates bond with one another, form long chains of molecules and become  “sticky“ as a result. The emulsifiers remain in the adhesive film, but no longer serve any purpose. The manufacturing of a dispersion adhesive tape is typically a fast, simplified process.

A more exclusive group of adhesive tapes is manufactured using a solid-based adhesive containing pure acrylate. A slower, more labour intensive manufacturing process than that required for acrylate dispersion adhesives. This type of acrylic tape, due to its robustness has for decades now been utilised in the aeronautical and automobile industries.

The Key differences between the two types of adhesive tape (Dispersion and Solid Acrylate) is the omission of the need for additional Resins when the tapes are manufactured in the Solid Acrylic adhesive process. In doing so the adhesive tape is at much less a risk of failing when exposed to higher / lower temperatures and humidity, impact of water and  slippage/ loss of adhesion over time.

Forcing the Issue 

There are two forces at play when considering adhesive joints: Adhesion; the force of holding the adhesive to a substrate and Cohesion; the adhesives ability to hold itself together.  Striking the correct balance between adhesion and cohesion makes for the ideal adhesive tape.

ADHESION - The tendency of dissimilar particles or surfaces to cling to one another

If the adhesive is in direct contact with the surface, attractive forces Van der Waals forces – will result between the two elements at a molecular level. The closer the adhesive comes to the surface, the more these forces will come into play and increase the strength of adhesion to the surface.

Adhesion explained

A similar principle of adhesion applies with the Gecko, which is able to walk upside-down to smooth surfaces such as panes of glass. This is made possible by the large number of very fine setae (hairs) on the feet of the Gecko, increasing the contact surface and thus facilitating sufficiently strong adhesive forces.

Tape Adhesion - Gecko Example

With these pressure activated solid acrylic adhesive tapes, the adhesive is "wetted" providing "the flow" to form strong clinging bonds at the molecular level –similar to what we witness in nature with geckos.

Put them under pressure 

The crucial point of note from the above images is the importance of direct and pressurized contact between the adhesive and the substrates to which is being taped to / sealed.  The adhesive flows around these structures and claws to the surface like a squirrel on a tree or grips the surface like a sloth wrapped around a branch.

Pressure activated adhesive tapes ensure that the adhesive forces are brought as close as possible together in order for Van der Waals forces to take effect

The increase of adhesion over time of a solid acrylic pressure activated tape is really what sets itself apart from the tackier dispersion based glues. The crucial point to note is that the solid acrylic based tapes bond to the substrates on a molecular level, penetrating much deeper into the substrate rather than relying on sticking to just the face of the substrate alone.  Adhesion alone however only tells half the story of an effective adhesive tape.

COHESION - Striking the correct balance between adhesion and cohesion makes the ideal adhesive tape.

Cohesion and adhesion

The Waiting Game:  The build-up of adhesive forces

Much of how we judge the suitability of airtightness tapes is down to how sticky we feel they are. The stickiness or lack thereof is typically decided by the simple finger or thumb test. Pressing a finger onto the face of the adhesive. The result?, Well it feels sticky, as it should do!

Although this initial tack will gave you an indication as to the stickiness of an adhesive tape, this really won’t tell you much, if anything, about how suitable the tape will be in holding an airtight seal even 3-4 months down the line and much less about how well things will remain stuck in 50+ years over the service life of a building.  The dispersion glues discussed above can be identified as being aggressively sticky initially. A widely held fact however is that this initial tack is synonymous with cheaper, low grade adhesive tape. These tapes being commonly adopted as household tapes and the standard Duct tape.

Soft adhesives (as found in Dispersion glue tapes) perform better in the ‘finger adhesion’ test, as they are better able to wet the surface of the thumb. This can lead to problems in practical construction applications, as soft adhesives generally have low cohesion forces.

It can take some time before an adhesive has flowed into a subsurface fully and established a strong bond with it. Adhesive strength is generally built up over a period of hours. The reason that manufacturers recommend that their adhesive tapes should be pressed into place can be explained by the mechanisms described above: an adhesive must be brought into close contact with a subsurface to be able to flow around and surround it.

Solid Arcylic Tape adhesion over time

The photo above illustrates the increase in bonding strength over the course of one day. The initial adhesion – after 20 minutes - shown on the left is adequate for initial airtight adhesion to a substrate however the image on the right shows a significant increase in the adhesive bond over the course of 24 hours with a much more robust bond as the adhesive is given time to penetrate deeper into the adjoining substrate.  

When we then compare this significant increase of adhesion with the two images below we see a real and distinct difference in the performance of the adhesive bonding over time from the dispersion adhesive tape (grey tape) to that of the solid acrylic tape (blue tape).  After 20 minutes this basic grey dispersion based tape gives an adequate initial tack.

What is most crucial however for adhesive tapes being used in construction is that this adhesion increases over time.

As can be seen after the 24 hours the tape offers no significant increase in adhesion can be seen peeling away quite easily from the face of the wooden substrate.

Dispersion Tape adhesion over time

The dispersion based adhesive tape lacks any real cohesive strength and fails when put under stress – delaminating away from the face of the substrate as it doesn’t possess sufficient cohesive strength, its adhesive unable to penetrate deep enough into the adjoining material or resist the stress of movement.

The solid acrylic based glue (blue tape) on the other hand forms a much more robust bond.

In our next blog we will look in detail at the impact that on-site conditions can have on the performance of an adhesive tape.

Including the impact that the presence of water can have on durability of the adhesive to remain stuck for the life time of the building.

Fintan Wallace Written By: Fintan Wallace (Architectural Technologist) Ecological Building Systems

 

 

Posted on Monday, 13 August 2018
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